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Ingredients

Ingredient Dictionary

AMMONIUM HYDROXIDE

Ammonium hydroxide is a solution of ammonia in water.

Molecular structure

How much products actually contain

No product states its amount yet.

Of the products containing it, 6 list it before the 1% line and 3 after it (usually 1% or less).

Products using this ingredient

8 of 8 confirmed · likeliest to carry enough first

Definition

Ammonium hydroxide is a solution of ammonia in water. It has a role as a food acidity regulator.

Source: PubChem

Cosmetic roles

Keeps pH steadyBUFFERINGMakes alcohol undrinkableDENATURANT

Safety & regulatory references

Argentina · Brazil

  • Maximum concentration permitted at final product : 6% calculated as NH3
  • Use conditions and warnings that must appear on the label : Above 2%: contains ammonia

ASEAN

  • Maximum authorised concentration in the finished cosmetic product : 6% calculated as NH3
  • Conditions of use and warning which must be printed on the labels : Above 2%: Contains ammonia

Source: MFDS (Korea) cosmetic regulatory information

Korea’s toxic-substance GHS classification: Danger · H400 (category 1) · H314 (category 1) · H331 (category 3) · +2 more

Source: Korea toxic substances GHS register (NIER)

Restriction III/4 · Other restriction: ban substances that deplete the ozone layer

Source: EU CosIng ingredient list

Reviewed by CIR: Final Report: Safety Assessment of Ammonia and Ammonium Hydroxide as Used in Cosmetics

Source: US Cosmetic Ingredient Review (CIR)

More data — names, identifiers, properties, test records, literature

Official labels & definitions

JCIA labelling name アンモニア水: 本品は、アンモニアの水溶液であり、次の化学式で表される。

Source: JCIA labelling names (Japan)

Names & identifiers

AMMONIUM HYDROXIDEINCI암모늄하이드록사이드Korean label name (MFDS standard)アンモニア水Japanese labelling name
CAS No.chemical registry number
1336-21-6
EC No.EU chemical inventory number
215-647-6
DTXSIDUS EPA chemical ID
DTXSID4020080
DTXCIDUS EPA compound ID
DTXCID8080
IUPAC
Ammonium hydroxide
Molecular formula
H5NO
Molecular weight
35.046 g/mol

Measured properties

Appearance
Ammonium hydroxide appears as a colorless aqueous solution. Concentration of ammonia ranges up to approximately 30%. Ammonia vapors (which arise from the solution) irritate the eyes. · Liquid, Other Solid, CBI, Gas Vapor
Odour
Intense, pungent, suffocating odor
Boiling point
38 °C (25%) · 36 °C @760 [mm Hg]
Melting point
-58 °C (25%) · -77 °C
Solubility
Exists only in solution · Solubility in water: miscible
Density
About 0.90 @ 25 °C/25 °C · Relative density (water = 1): 0.9 (25%)
pH
pH= 11.6 (1.0 N solution), 11.1 (0.1 N solution), 10.6 (0.01 N solution)
Dissociation constant
pKb= 4.767, Kb= 1.710X10-5 at 20 °C, pKb= 4.751, Kb= 1.774X10-5 at 25 °C, pKb= 4.740, Kb= 1.820X10-5 at 30 °C
Colour
colourless
Odour threshold
50 ppm
Melting/freezing point
-77 ℃
Initial boiling point and range
36 ℃
Vapour pressure
48 ㎪(20℃, 25%)
Water solubility
100 g/100㎖(25℃ (est.))
Vapour density
1.2 (0.6-1.2)
Relative density
0.9
n-Octanol/water partition coefficient (Kow)
-2.66 (est.)
Molecular weight
35.05

Values measured on the substance itself. The KOSHA data are a reference for writing and reviewing safety data sheets, not a specification for a commercial raw material.

Source: PubChem · KOSHA safety data sheets (Korea)

What products actually use it for

What the 295 products reported to the US EPA with this ingredient use it for. Products outside cosmetics are included, so the top few rows are its main uses.

  • pH regulating agent203
  • No specific technical function16
  • Cleaning agent9
  • Processing aids not otherwise specified8
  • Solvent7
  • Binder6
  • Soil amendments4
  • Surfactant (surface active agent)4
25 other uses
  • Intermediate3
  • Catalyst2
  • Lubricating agent2
  • Bleaching agent2
  • Pharmaceutical (EPA)2
  • Adhesion/cohesion promoter2
  • Diluent2
  • Refrigerants2
  • Chemical reaction regulator2
  • Etching agent2
  • Stabilizing agent2
  • Preservative2
  • Tanning agents not otherwise specified1
  • Anti-scaling agent1
  • Flame retardant1
  • Flavouring and nutrient1
  • Surface modifier1
  • Leavening agent (EPA)1
  • Solubility enhancer1
  • Reducing agent1
  • Corrosion inhibitor1
  • Solids separation (precipitating) agent, not other1
  • Semiconductor and photovoltaic agent1
  • Plating agent1
  • Abrasive1

Source: US EPA CompTox dashboard

Irritation and sensitisation studies

7 skin studies and 3 eye studies are on record.

Classed as highly irritating1

The study conclusions largely agree (100%). These tests are on the raw material itself; irritation at the amount in a finished product is a different question.

See all 10 studies
  • Classification not possible
    Skin Sensitization · Screening
  • Category 1
    Skin Irritation · Screening
  • Skin Corr. 1B
    Skin Irritation · Authoritative
  • Category 6.3A (Category 2)
    Skin Irritation · Read Across
  • Category 8.2B (Category 1B)
    Skin Irritation · Read Across
  • Category 8.2C (Category 1C)
    Skin Irritation · Read Across
  • Skin corrosion/irritation - Category 1
    Skin Irritation · Screening
  • Category 1
    Eye Irritation · Screening
  • Category 8.3A (Category 1)
    Eye Irritation · Read Across
  • Category 6.4A (Category 2A)
    Eye Irritation · Read Across

Source: US EPA CompTox dashboard

Related literature

Linked databases 18