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Ingredients

Ingredient Dictionary

BENZYL ALCOHOL

Benzyl alcohol is an aromatic alcohol that consists of benzene bearing a single hydroxymethyl substituent.

Molecular structure

How much products actually contain

No product states its amount yet.

Of the products containing it, 166 list it before the 1% line and 678 after it (usually 1% or less).

Products using this ingredient

12 of 840 confirmed · likeliest to carry enough first · See all 840

Definition

Benzyl alcohol is an aromatic alcohol that consists of benzene bearing a single hydroxymethyl substituent. It has a role as an antioxidant, a metabolite, a solvent and a fragrance.

Source: PubChem

US FDA substance register · UNII LKG8494WBH · registered name Benzyl alcohol · single chemical substance

Source: US FDA Unique Ingredient Identifier (UNII)

Benzyl Alcohol is an aromatic alcohol that conforms to the formula:

Cosmetic roles

Gives the product a scentPERFUMINGBase that dissolves other ingredientsSOLVENTStops microbes growing in the productPRESERVATIVEAdjusts thicknessVISCOSITY CONTROLLING

Safety & regulatory references

Restricted
International fragrance standard (IFRA) · United Kingdom
Allowed preservative
United Kingdom

Source: ASEAN Cosmetic Directive · EU Cosmetics Regulation · IFRA fragrance standards · MFDS (Korea) cosmetic regulatory information · UK cosmetics regulations (OPSS) · Taiwan FDA cosmetic ingredients

Argentina · Brazil

  • Maximum concentration permitted at final product : 1.0%

ASEAN

  • Field of application and/or use : (a) Solvents (b) fragrance/aromatic compositions/their raw materials
  • Other limitations and requirements : As a preservative, see Annex VI, Part1, No. 34

Taiwan · China

  • Maximum concentration : 1%

South Korea

  • Maximum concentration : 1.0%

European Union

  • Other : For purposes other than inhibiting the development of microorganisms in the product. This purpose has to be apparent from the presentation of the product. The presence of the substance shall be indicated in the list of ingredients referred to in Article 19(1), point (g), when its concentration exceeds: — 0,001 % in leave-on products — 0,01 % in rinse-off products
  • Maximum concentration in ready for use preparation : 1.0%

Source: MFDS (Korea) cosmetic regulatory information

Not classified under Korea’s toxic-substance GHS list · existing chemical substance

Source: Korea toxic substances GHS register (NIER)

EU Cosmetics Regulation, Annex V (allowed preservatives), entry 34 · maximum concentration 1.0%

Source: EU allowed preservatives (Annex V)

EU Cosmetics Regulation, Annex III (restricted substances), entry 45 · applies to (a) Solvent (b) Fragrance/ aromatic compositions/ their raw materials

Source: EU restricted substances (Annex III)

Restriction III/45 and V/34

Source: EU CosIng ingredient list

Reviewed by CIR: Final Report on the Safety Assessment of Benzyl Alcohol, Benzoic Acid, and Sodium Benzoate

Source: US Cosmetic Ingredient Review (CIR)

Reviewed by CIR: Safety Assessment of Benzyl Alcohol, Benzoic Acid and its Salts, and Benzyl Benzoate

Source: US Cosmetic Ingredient Review (CIR)

Reviewed by CIR: Benzyl Alcohol, Benzoic Acid, Sodium Benzoate

Source: US Cosmetic Ingredient Review (CIR)

More data — names, identifiers, properties, test records, literature

Official labels & definitions

JCIA labelling name ベンジルアルコール: 本品は、次の化学式で表される芳香族アルコールである。

Source: JCIA labelling names (Japan)

Names & identifiers

BENZYL ALCOHOLINCI벤질알코올Korean label name (MFDS standard)BenzenemethanolSynonymベンジルアルコールJapanese labelling name
CAS No.chemical registry number
100-51-6
EC No.EU chemical inventory number
202-859-9
DTXSIDUS EPA chemical ID
DTXSID5020152
DTXCIDUS EPA compound ID
DTXCID70152
IUPAC
Phenylmethanol
Molecular formula
C7H8O
Molecular weight
108.14 g/mol

Measured properties

Appearance
Benzyl alcohol appears as a clear colorless liquid with a pleasant odor. Slightly denser than water. Flash point 194 °F. Boiling point 401 °F. Contact may irritate skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals. · Gas Vapor, Liquid, Wet Solid, Other Solid, CBI
Odour
Faint aromatic odor
Boiling point
401 °F at 760 mmHg (NTP, 1992) · 205.3 °C, 478 K, 402 °F
Melting point
4.5 °F (NTP, 1992) · -15..2 °C, 258 K, 5 °F
Solubility
10 to 50 mg/mL at 70 °F (NTP, 1992) · 33 mg/mL, clear, colorless
Density
1.05 at 1515 °F (USCG, 1999) - Denser than water, will sink · 1.0419 g/cu cm at 24 °C
Melting/freezing point
-15 ℃
Initial boiling point and range
205 ℃
Flash point
93 ℃(c.c.)
Upper/lower flammability or explosive limits
13 / 1.3 %
Vapour pressure
13.2 ㎩ (20℃)
Water solubility
4.29 g/100㎖ (25℃)
Vapour density
3.7
Relative density
1.04
n-Octanol/water partition coefficient (Kow)
1.1
Auto-ignition temperature
436 ℃

Values measured on the substance itself. The KOSHA data are a reference for writing and reviewing safety data sheets, not a specification for a commercial raw material.

Source: PubChem · KOSHA safety data sheets (Korea)

What products actually use it for

What the 889 products reported to the US EPA with this ingredient use it for. Products outside cosmetics are included, so the top few rows are its main uses.

  • Fragrance741
  • Preservative28
  • Solvent24
  • Diluent23
  • Solubility enhancer16
  • Hardener15
  • Viscosity modifier9
  • Pharmaceutical (EPA)6
15 other uses
  • Processing aids not otherwise specified4
  • Plasticizer4
  • Flavouring and nutrient3
  • Cleaning agent3
  • Biocide3
  • Emulsifier1
  • Intermediate1
  • Photosensitive agent1
  • Corrosion inhibitor1
  • Monomers1
  • Dispersing agent1
  • Deodorizer1
  • Coalescing agent1
  • Antioxidant1
  • Binder1

Source: US EPA CompTox dashboard

Irritation and sensitisation studies

4 skin studies and 4 eye studies are on record.

Classed as low2

The study conclusions largely agree (100%). These tests are on the raw material itself; irritation at the amount in a finished product is a different question.

See all 8 studies
  • Not classified
    Skin Irritation · Screening
  • Classification not possible
    Skin Sensitization · Screening
  • Not likely to be sensitizing
    skin sensitisation: in vivo (non-LLNA) · Screening · according to OECD Guideline 406 (Skin Sensitisation)
  • Category 6.5B (Category 1)
    Skin Sensitization · Read Across
  • Category 2
    Eye Irritation · Screening
  • Serious eye damage/eye irritation - Category 2
    Eye Irritation · Screening
  • Category 6.4A (Category 2A)
    Eye Irritation · Read Across
  • Eye irritation - category 2A
    Eye Irritation · Screening

Source: US EPA CompTox dashboard

Related literature

Linked databases 30