Sodium hydrogensulfite is an inorganic sodium salt having hydrogensulfite as the counterion.
How much products actually contain
No product states its amount yet.
Of the products containing it, 6 list it before the 1% line and 21 after it (usually 1% or less).
Products using this ingredient
12 of 27 confirmed · likeliest to carry enough first · See all 27
Paul MitchellPaul Mitchell Sculpting Spray Gel
OuidadOuidad Curl Shaper Out of Thin (H)air Volumizing Jelly
OuidadOuidad Curl Shaper Bounce Back Reactivating Mist
OuidadOuidad Water Works Clarifying Shampoo
CurlsmithCurlsmith Bouncy Strength Volume Foam
LabottachVenolite 4 Patches
Paul MitchellPaul Mitchell Extra-Body Sculpting Gel
BevelBevel Bevel Exfoliating Toner
Paul MitchellPaul Mitchell Extra-Body Sculpting Foam
PATTERN BeautyPATTERN Beauty Edge Control
MorpheMorphe Micro Manager Gripping Brow Gel
EltaMDEltaMD Renew Eye Gel
Definition
Sodium hydrogensulfite is an inorganic sodium salt having hydrogensulfite as the counterion. It has a role as a mutagen, an allergen, a reducing agent, a food antioxidant and a food colour retention agent. It is an inorganic sodium salt and a sulfite salt. It contains a hydrogensulfite.
Source: PubChem
US FDA substance register · UNII TZX5469Z6I · registered name Sodium bisulfite · single chemical substance
Sodium Bisulfite is the inorganic salt that conforms to the formula:
Cosmetic roles
Safety & regulatory references
- Restricted
- China · South Korea · Taiwan
Source: MFDS (Korea) cosmetic regulatory information
Argentina · Brazil
- Field of application and/or use : (a) an oxidizer in hair dyes (b) straighteners hair products (c) facial sunless d) Other self-tanning
- Maximum concentration permitted at final product : (a) 0,67% expressed as SO 2free (b) 6.7% expressed as SO 2 free (c) 0.45% expressed as SO 2free d) 0,40% expressed as SO 2free
ASEAN
- Field of application and/or use : (a) Oxidative hair dye products (b) Hair straightening products (c) Self- tanning products for the face (d) Other self- tanning products
- Maximum authorised concentration in the finished cosmetic product : (a) 0.67 % expressed as free SO2 (b) 6.7 % expressed as free SO2 (c) 0.45 % expressed as free SO2 (d) 0.40 % expressed as free SO2
- Other limitations and requirements : For purposes other than inhibiting the development of microorganisms in the product. This purpose has to be apparent from the presentation of the product As a preservative, see Annexe VI, Part 1, No 9
European Union
- Product Type, body parts : (a) Oxidative hair dye products (b) Hair straightening products (c) Self-tanning products for the face (d) Other self-tanning products
- Maximum concentration in ready for use preparation : (a) 0.67% (as free SO2) (b) 6.7% (as free SO2) (c) 0.45% (as free SO2) (d) 0.40% (as free SO2)
- Other : For purposes other than inhibiting the development of micro-organisms in the product. This purpose has to be apparent from the presentation of the product
- Maximum concentration in ready for use preparation : 0.2% (as free SO2)
Source: MFDS (Korea) cosmetic regulatory information
Not classified under Korea’s toxic-substance GHS list · existing chemical substance
Restriction III/99 V/9
Source: EU CosIng ingredient list
Reviewed by CIR: Sulfites
Reviewed by CIR: Final Report on the Safety Assessment of Sodium Sulfite, Potassium Sulfite, Ammonium Sulfite, Sodium Bisulfite, Ammonium Bisulfite, Sodium Metabisulfite, and Potassium Metabisulfite
More data — names, identifiers, properties, test records, literature
Official labels & definitions
JCIA labelling name 亜硫酸水素Na: 本品は、亜硫酸の一ナトリウム塩であり、次の化学式で表される。
Source: JCIA labelling names (Japan)
Names & identifiers
- CAS No.chemical registry number
- 7631-90-5
- EC No.EU chemical inventory number
- 231-548-0
- DTXSIDUS EPA chemical ID
- DTXSID8034902
- DTXCIDUS EPA compound ID
- DTXCID6014902
- IUPAC
- Sodium hydrogen sulfite
- Molecular formula
- HNaO3S
- Molecular weight
- 104.05 g/mol
Measured properties
- Colour
- white
- Melting/freezing point
- &, lt, ℉
- Initial boiling point and range
- &, gt, 212 ℉ (760 ㎜Hg)
- Relative density
- 1.48
- Molecular weight
- 104.062
Values measured on the substance itself. The KOSHA data are a reference for writing and reviewing safety data sheets, not a specification for a commercial raw material.
Source: KOSHA safety data sheets (Korea)
What products actually use it for
What the 71 products reported to the US EPA with this ingredient use it for. Products outside cosmetics are included, so the top few rows are its main uses.
- Processing aids not otherwise specified20
- Thickening agent9
- Preservative5
- Reducing agent4
- Surfactant (surface active agent)3
- Corrosion inhibitor3
- Antioxidant3
- pH regulating agent2
19 other uses
- Intermediate2
- Stabilizing agent2
- Cleaning agent2
- Dye1
- Fixing agent (mordant)1
- Solids separation (precipitating) agent, not other1
- Chemical reaction regulator1
- Hair waving or straightening (EPA)1
- Polymerization promoter1
- Soil amendments1
- Oxidizing agent1
- Biocide1
- Tanning agents not otherwise specified1
- Food preservative (EPA)1
- Surface modifier1
- Filler1
- Flavouring and nutrient1
- Bleaching agent1
- Plasticizer1
Source: US EPA CompTox dashboard
Irritation and sensitisation studies
5 skin studies and 3 eye studies are on record.
The study conclusions largely agree (100%). These tests are on the raw material itself; irritation at the amount in a finished product is a different question.
See all 8 studies
- Classification not possible
Skin Sensitization · Screening - Category 6.3A (Category 2)
Skin Irritation · Read Across - Category 6.5B (Category 1)
Skin Sensitization · Read Across - Classification not possible
Skin Irritation · Screening - Studies Indicate No Significant Irritation
skin irritation: in vivo · Screening · OECD Guideline 404 (Acute Dermal Irritation / Corrosion) 2002-04-24 equivalent or similar to - Category 6.4A (Category 2A)
Eye Irritation · Read Across - Category 2B
Eye Irritation · Screening - Eye damage - category 1
Eye Irritation · Screening
Source: US EPA CompTox dashboard
Related literature
- Final Report on the Safety Assessment of Sodium Sulfite, Potassium Sulfite, Ammonium Sulfite, Sodium Bisulfite, Ammonium Bisulfite, Sodium Metabisulfite and Potassium Metabisulfite · 2003
- Bromfenac with Sodium Bisulfite Inducing Contact Dermatitis and Corneal Ring Infiltrate: A Case Report · 2026
- Menadione Sodium Bisulfite Loaded Rhamnolipid Based Solid Lipid Nanoparticle as Skin Lightener Formulation: A Green Production Beside In Vitro/In Vivo Safety Index Evaluation · 2024
- Dangers of Propofol in Cosmetic Surgery · 2003
- Can Chemical Burns and Allergic Contact Dermatitis From Higher Concentrations of Methylchloroisothiazolinone/Methylisothiazolinone be Prevented? · 1998
Linked databases 22
- Australian Industrial Chemicals Inventory (AICIS)
- ChEBI
- ChEMBL
- China inventory of existing ingredients (IECIC)
- EU CosIng ingredient list 2
- JCIA labelling names (Japan)
- Korea Cosmetic Association ingredient dictionary
- Korea toxic substances GHS register (NIER)
- KOSHA safety data sheets (Korea)
- MFDS (Korea) cosmetic ingredient register 2
- MFDS (Korea) cosmetic regulatory information 2 3
- NIST Chemistry WebBook
- PubChem
- Tlooto literature search 2 3 4 5
- UniChem cross-reference IDs
- US Cosmetic Ingredient Review (CIR) 2 3
- US EPA CompTox dashboard 2
- US EPA DSSTox chemical database
- US FDA substance registration (GSRS)
- US FDA Unique Ingredient Identifier (UNII)
- Wikidata
- Wikipedia · Korean · English · Japanese · Chinese