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Ingredients

Ingredient Dictionary

SODIUM BISULFITE

Sodium hydrogensulfite is an inorganic sodium salt having hydrogensulfite as the counterion.

Molecular structure

How much products actually contain

No product states its amount yet.

Of the products containing it, 6 list it before the 1% line and 21 after it (usually 1% or less).

Products using this ingredient

12 of 27 confirmed · likeliest to carry enough first · See all 27

Definition

Sodium hydrogensulfite is an inorganic sodium salt having hydrogensulfite as the counterion. It has a role as a mutagen, an allergen, a reducing agent, a food antioxidant and a food colour retention agent. It is an inorganic sodium salt and a sulfite salt. It contains a hydrogensulfite.

Source: PubChem

US FDA substance register · UNII TZX5469Z6I · registered name Sodium bisulfite · single chemical substance

Source: US FDA Unique Ingredient Identifier (UNII)

Sodium Bisulfite is the inorganic salt that conforms to the formula:

Cosmetic roles

Stops microbes growing in the productPRESERVATIVESlows spoilage by oxygenANTIOXIDANTReduces other ingredientsREDUCINGCurls or straightens hairHAIR WAVING OR STRAIGHTENING

Safety & regulatory references

Restricted
China · South Korea · Taiwan

Source: MFDS (Korea) cosmetic regulatory information

Argentina · Brazil

  • Field of application and/or use : (a) an oxidizer in hair dyes (b) straighteners hair products (c) facial sunless d) Other self-tanning
  • Maximum concentration permitted at final product : (a) 0,67% expressed as SO 2free (b) 6.7% expressed as SO 2 free (c) 0.45% expressed as SO 2free d) 0,40% expressed as SO 2free

ASEAN

  • Field of application and/or use : (a) Oxidative hair dye products (b) Hair straightening products (c) Self- tanning products for the face (d) Other self- tanning products
  • Maximum authorised concentration in the finished cosmetic product : (a) 0.67 % expressed as free SO2 (b) 6.7 % expressed as free SO2 (c) 0.45 % expressed as free SO2 (d) 0.40 % expressed as free SO2
  • Other limitations and requirements : For purposes other than inhibiting the development of microorganisms in the product. This purpose has to be apparent from the presentation of the product As a preservative, see Annexe VI, Part 1, No 9

European Union

  • Product Type, body parts : (a) Oxidative hair dye products (b) Hair straightening products (c) Self-tanning products for the face (d) Other self-tanning products
  • Maximum concentration in ready for use preparation : (a) 0.67% (as free SO2) (b) 6.7% (as free SO2) (c) 0.45% (as free SO2) (d) 0.40% (as free SO2)
  • Other : For purposes other than inhibiting the development of micro-organisms in the product. This purpose has to be apparent from the presentation of the product
  • Maximum concentration in ready for use preparation : 0.2% (as free SO2)

Source: MFDS (Korea) cosmetic regulatory information

Not classified under Korea’s toxic-substance GHS list · existing chemical substance

Source: Korea toxic substances GHS register (NIER)

Restriction III/99 V/9

Source: EU CosIng ingredient list

Reviewed by CIR: Sulfites

Source: US Cosmetic Ingredient Review (CIR)

Reviewed by CIR: Final Report on the Safety Assessment of Sodium Sulfite, Potassium Sulfite, Ammonium Sulfite, Sodium Bisulfite, Ammonium Bisulfite, Sodium Metabisulfite, and Potassium Metabisulfite

Source: US Cosmetic Ingredient Review (CIR)

More data — names, identifiers, properties, test records, literature

Official labels & definitions

JCIA labelling name 亜硫酸水素Na: 本品は、亜硫酸の一ナトリウム塩であり、次の化学式で表される。

Source: JCIA labelling names (Japan)

Names & identifiers

SODIUM BISULFITEINCI소듐바이설파이트Korean label name (MFDS standard)Sulfurous acid, monosodium saltSynonym亜硫酸水素NaJapanese labelling name
CAS No.chemical registry number
7631-90-5
EC No.EU chemical inventory number
231-548-0
DTXSIDUS EPA chemical ID
DTXSID8034902
DTXCIDUS EPA compound ID
DTXCID6014902
IUPAC
Sodium hydrogen sulfite
Molecular formula
HNaO3S
Molecular weight
104.05 g/mol

Measured properties

Colour
white
Melting/freezing point
&amp, lt, ℉
Initial boiling point and range
&amp, gt, 212 ℉ (760 ㎜Hg)
Relative density
1.48
Molecular weight
104.062

Values measured on the substance itself. The KOSHA data are a reference for writing and reviewing safety data sheets, not a specification for a commercial raw material.

Source: KOSHA safety data sheets (Korea)

What products actually use it for

What the 71 products reported to the US EPA with this ingredient use it for. Products outside cosmetics are included, so the top few rows are its main uses.

  • Processing aids not otherwise specified20
  • Thickening agent9
  • Preservative5
  • Reducing agent4
  • Surfactant (surface active agent)3
  • Corrosion inhibitor3
  • Antioxidant3
  • pH regulating agent2
19 other uses
  • Intermediate2
  • Stabilizing agent2
  • Cleaning agent2
  • Dye1
  • Fixing agent (mordant)1
  • Solids separation (precipitating) agent, not other1
  • Chemical reaction regulator1
  • Hair waving or straightening (EPA)1
  • Polymerization promoter1
  • Soil amendments1
  • Oxidizing agent1
  • Biocide1
  • Tanning agents not otherwise specified1
  • Food preservative (EPA)1
  • Surface modifier1
  • Filler1
  • Flavouring and nutrient1
  • Bleaching agent1
  • Plasticizer1

Source: US EPA CompTox dashboard

Irritation and sensitisation studies

5 skin studies and 3 eye studies are on record.

Classed as low1

The study conclusions largely agree (100%). These tests are on the raw material itself; irritation at the amount in a finished product is a different question.

See all 8 studies
  • Classification not possible
    Skin Sensitization · Screening
  • Category 6.3A (Category 2)
    Skin Irritation · Read Across
  • Category 6.5B (Category 1)
    Skin Sensitization · Read Across
  • Classification not possible
    Skin Irritation · Screening
  • Studies Indicate No Significant Irritation
    skin irritation: in vivo · Screening · OECD Guideline 404 (Acute Dermal Irritation / Corrosion) 2002-04-24 equivalent or similar to
  • Category 6.4A (Category 2A)
    Eye Irritation · Read Across
  • Category 2B
    Eye Irritation · Screening
  • Eye damage - category 1
    Eye Irritation · Screening

Source: US EPA CompTox dashboard

Related literature

Linked databases 22