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Ingredients

Ingredient Dictionary

SODIUM SULFITE

Sodium sulfite is an inorganic sodium salt having sulfite as the counterion.

Molecular structure

How much products actually contain

No product states its amount yet.

Of the products containing it, 10 list it before the 1% line and 48 after it (usually 1% or less).

Products using this ingredient

12 of 56 confirmed · likeliest to carry enough first · See all 56

Definition

US FDA substance register · UNII VTK01UQK3G · registered name Sodium Sulfite · single chemical substance

Source: US FDA Unique Ingredient Identifier (UNII)

Sodium sulfite is an inorganic sodium salt having sulfite as the counterion. It has a role as a reducing agent and a food preservative. It is an inorganic sodium salt and a sulfite salt. It contains a sulfite.

Source: PubChem

Sodium Sulfite is the inorganic salt that conforms to the formula:

Cosmetic roles

Curls or straightens hairHAIR WAVING OR STRAIGHTENINGReduces other ingredientsREDUCINGSlows spoilage by oxygenANTIOXIDANT

Safety & regulatory references

Restricted
China · South Korea · Taiwan
Allowed preservative
Taiwan · United Kingdom

Source: MFDS (Korea) cosmetic regulatory information · EU Cosmetics Regulation · Taiwan FDA cosmetic ingredients · UK cosmetics regulations (OPSS)

Argentina · Brazil

  • Field of application and/or use : (a) an oxidizer in hair dyes (b) straighteners hair products (c) facial sunless d) Other self-tanning
  • Maximum concentration permitted at final product : (a) 0,67% expressed as SO 2free (b) 6.7% expressed as SO 2 free (c) 0.45% expressed as SO 2free d) 0,40% expressed as SO 2free

ASEAN

  • Field of application and/or use : (a) Oxidative hair dye products (b) Hair straightening products (c) Self- tanning products for the face (d) Other self- tanning products
  • Maximum authorised concentration in the finished cosmetic product : (a) 0.67 % expressed as free SO2 (b) 6.7 % expressed as free SO2 (c) 0.45 % expressed as free SO2 (d) 0.40 % expressed as free SO2
  • Other limitations and requirements : For purposes other than inhibiting the development of microorganisms in the product. This purpose has to be apparent from the presentation of the product As a preservative, see Annexe VI, Part 1, No 9

European Union

  • Product Type, body parts : (a) Oxidative hair dye products (b) Hair straightening products (c) Self-tanning products for the face (d) Other self-tanning products
  • Maximum concentration in ready for use preparation : (a) 0.67% (as free SO2) (b) 6.7% (as free SO2) (c) 0.45% (as free SO2) (d) 0.40% (as free SO2)
  • Other : For purposes other than inhibiting the development of micro-organisms in the product. This purpose has to be apparent from the presentation of the product
  • Maximum concentration in ready for use preparation : 0.2% (as free SO2)

Source: MFDS (Korea) cosmetic regulatory information

Not classified under Korea’s toxic-substance GHS list · existing chemical substance

Source: Korea toxic substances GHS register (NIER)

Restriction III/99 V/9

Source: EU CosIng ingredient list

Reviewed by CIR: Sulfites

Source: US Cosmetic Ingredient Review (CIR)

Reviewed by CIR: Final Report on the Safety Assessment of Sodium Sulfite, Potassium Sulfite, Ammonium Sulfite, Sodium Bisulfite, Ammonium Bisulfite, Sodium Metabisulfite, and Potassium Metabisulfite

Source: US Cosmetic Ingredient Review (CIR)

More data — names, identifiers, properties, test records, literature

Official labels & definitions

JCIA labelling name 亜硫酸Na: 本品は、亜硫酸の二ナトリウム塩であり、次の化学式で表される。

Source: JCIA labelling names (Japan)

Names & identifiers

SODIUM SULFITEINCI소듐설파이트Korean label name (MFDS standard)Sulfurous acid, disodium saltSynonym亜硫酸NaJapanese labelling name
CAS No.chemical registry number
7757-83-7
EC No.EU chemical inventory number
231-821-4
DTXSIDUS EPA chemical ID
DTXSID2044260
DTXCIDUS EPA compound ID
DTXCID0024260
IUPAC
Disodium sulfite
Molecular formula
Na2O3S
Molecular weight
126.04 g/mol

Measured properties

Appearance
Sodium sulfite is a white odorless powder. Density 2.633 g / cm3. Moderately toxic. Sinks in water and dissolves slowly. Also transported as a heptahydrate Na2SO3.7H2O. · Other Solid, Dry Powder, CBI, Large Crystals, Liquid
Odour
Odorless · odourless
Boiling point
Decomposes (NTP, 1992) · Decomposes
Melting point
Decomposes (NTP, 1992) · 911 °C
Solubility
Soluble in 3.2 parts (NTP, 1992) · Colorless, monoclinic crystals, demsity: 1.56 g/cu cm, solubility: 30.7 g/100 g water at 25 °C, slightly solluble in ethanol, unstable /Sodium sulfite heptahydrate/
Density
2.633 at 59 °F (USCG, 1999) - Denser than water, will sink · 2.63 g/cu cm
Stability
It is fairly stable and does not oxidize as readily as hydrated sulfite. · Unstable, oxidizing in air to sulfate /heptahydrate/
pH
8,5-11,5 (anhydrous: 10 % solution, heptahydrate: 20 % solution) · pH about 9
Colour
white
Melting/freezing point
&amp, gt, 500 ℃
Initial boiling point and range
&amp, gt, 100 ℃
Flash point
&amp, gt, 93.3 ℃
Vapour pressure
0.1 ㎜Hg (&amp, lt, 0.1 mmHg)
Water solubility
230000 ㎎/ℓ
Relative density
2.63
n-Octanol/water partition coefficient (Kow)
-4
Molecular weight
126.04

Values measured on the substance itself. The KOSHA data are a reference for writing and reviewing safety data sheets, not a specification for a commercial raw material.

Source: PubChem · KOSHA safety data sheets (Korea)

What products actually use it for

What the 108 products reported to the US EPA with this ingredient use it for. Products outside cosmetics are included, so the top few rows are its main uses.

  • Corrosion inhibitor42
  • Preservative12
  • Stabilizing agent10
  • Processing aids not otherwise specified10
  • Filler5
  • pH regulating agent4
  • Hair waving or straightening (EPA)3
  • Antioxidant3
15 other uses
  • Reducing agent2
  • Oxidizing agent2
  • Flux agent2
  • Fixing agent (mordant)2
  • Food preservative (EPA)1
  • Photosensitive agent1
  • Dye1
  • Bleaching agent1
  • Brightener1
  • Fragrance1
  • Plasticizer1
  • Intermediate1
  • Surfactant (surface active agent)1
  • Solvent1
  • Softener and conditioner1

Source: US EPA CompTox dashboard

Irritation and sensitisation studies

2 skin studies and 2 eye studies are on record.

Classed as low2

The study conclusions largely agree (100%). These tests are on the raw material itself; irritation at the amount in a finished product is a different question.

See all 4 studies
  • Studies Indicate No Significant Irritation
    skin irritation: in vivo · Screening · OECD Guideline 404 (Acute Dermal Irritation / Corrosion) , adopted 1981-05-12 equivalent or similar to
  • Not likely to be sensitizing
    skin sensitisation: in vivo (LLNA) · Screening · according to OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) , 2002-04-24
  • Eye damage - category 1
    Eye Irritation · Screening
  • Studies Indicate No Significant Irritation
    eye irritation: in vivo · Screening · OECD Guideline 405 (Acute Eye Irritation / Corrosion) equivalent or similar to

Source: US EPA CompTox dashboard

Related literature

Linked databases 24