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Ingredients

Ingredient Dictionary

CITRIC ACID

Molecular structure

How much products actually contain

38 products state the amountmedian 0.01%

  • under 0.01% 18
  • 0.01–0.1% 18
  • 0.1–1% 2
  • 1% or more 0

Amounts are mostly stated by products named after the ingredient, so they may lean towards token amounts.

Of the products containing it, 2,224 list it before the 1% line and 3,353 after it (usually 1% or less).

Products using this ingredient

12 of 5,561 confirmed · likeliest to carry enough first · See all 5,561

Definition

Citric Acid is the organic acid that conforms to the formula:

Cosmetic roles

Keeps pH steadyBUFFERINGListed as a fragrance-composition material (not a claim that it adds scent)FRAGRANCEBinds metal ions to prevent spoilageCHELATING

Safety & regulatory references

Argentina · Brazil

  • Maximum concentration permitted at final product : 0,2%, correspondente a 0,0024% de prata.
  • Other limitations and requirements : Proibido em produtos para uso bucal e em produtos para a área dos olhos.

Canada

  • <Alpha-hydroxy acids, including polyhydroxy acids and bionic acids with alpha hydroxyl groups, and their salts Citric acid>
  • Conditions of Use by product type : (a) Products for use on the skin for consumer use. Manufacturer or importer to provide pH levels. (b) Products for use on the skin for professional use: Manufacturer must provide Health Canada with evidence of safety including: 1. pH levels 2. AHA concentrations 3. Directions for use 4. Clinical studies demonstrating minimal skin irritation (c) Products intended to be diluted in bath water may contain levels of AHAs exceeding 10% (d) Other cosmetics (e) Any cosmetics
  • Maximum Concentration Permitted : (a) Between 3% and 18% total mono-AHA equivalents with a pH equal to or greater than 3.5 (b) Between 18% and 30% total mono-AHA equivalents and/or a pH between 3.0 to 3.5 (d) Between 3% and 30% total mono-AHA equivalents with a pH equal to or greater than 3.0 (e) 3%
  • Warnings and Cautionary Statements: (to the effect of) : (a) and (b) : "Use only as directed", "Avoid contact with the eyes", "If irritation persists, discontinue use and consult a physician", "It is recommended that prior to exposure to the sun, users cover areas where AHAs have been applied with sunscreen" Product labels should contain appropriate directions regarding frequency and/or duration of use. (b only) "For professional use only" (d) "Use only as directed", "Avoid contact with eyes", "Discontinue use if rash or irritation occurs"
  • Conditions of Use by product type : See "Alpha-hydroxy acids".

Taiwan

  • <Maximum concentration : α-Hydroxy acids(AHA)>
  • Maximum concentration : pH≧3.5;

Source: MFDS (Korea) cosmetic regulatory information

SCCS opinion: Opinion on Citric acid (and) Silver Citrate; Position paper on the Safety of alpha-Hydroxy Acids; Updated position paper concerning consumer Safety of alpha-hydroxy acids

Source: EU CosIng ingredient list

Reviewed by CIR: Safety Assessment of Citric Acid, Inorganic Citrate Salts, and Alkyl Citrate Esters as Used in Cosmetics

Source: US Cosmetic Ingredient Review (CIR)

More data — names, identifiers, properties, test records, literature

Official labels & definitions

JCIA labelling name クエン酸: 本品は、次の化学式で表される有機酸である。

Source: JCIA labelling names (Japan)

Names & identifiers

CITRIC ACIDINCI시트릭애씨드Korean label name (MFDS standard)クエン酸Japanese labelling name
CAS No.chemical registry number
5949-29-1
CAS No.chemical registry number
77-92-9
CAS No.chemical registry number
77-92-9 / 5949-29-1
EC No.EU chemical inventory number
201-069-1

Measured properties

Appearance
Citric acid appears as colorless, odorless crystals with an acid taste. Denser than water. (USCG, 1999) · Other Solid, Dry Powder, CBI, Large Crystals, Liquid
Odour
Odorless
Boiling point
Decomposes (NTP, 1992) · Decomposes
Melting point
307 °F (anhydrous) (NTP, 1992) · 153 °C
Solubility
greater than or equal to 100 mg/mL at 72 °F (NTP, 1992) · 592000 mg/L (at 20 °C)
Density
1.54 at 68 °F (USCG, 1999) - Denser than water, will sink · 1.665 g/cu cm at 20 °C
Viscosity
2.549 cP 30% aqueous solution at 20 °C
Dissociation constant
2.79 · pKa = 2.79

Values measured on the substance itself, not a specification for a commercial raw material.

Source: PubChem

Related literature

Linked databases 18